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The first step in decontaminating oneself after exposure to an OC (oleoresin capsicum) agent is to wash clothes separately. This option is correct because OC agents, commonly known as pepper spray, can adhere to clothing and continue to cause irritation even after the initial exposure. By washing contaminated clothing separately, you help prevent the spread of the agent to other clothes and ensure that any residue is effectively removed.

Taking a hot shower is not advisable immediately after exposure, as hot water can exacerbate the burning sensation. Applying lotion to the affected area may cause more irritation and is not an effective means of decontamination. Using rubbing alcohol is not recommended, as it may also cause further irritation and does not neutralize the OC agent effectively. The focus should be on removing and isolating contaminated clothing as the crucial first step in the decontamination process.